- Joined
- Oct 18, 2014
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- 620
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- Location
- Western North Carolina (NJ transplant)
- Your Mac's Specs
- MBP 13", 2020, 2.3 Ghz, Quad core i7, 16gb, 1 TB, Iris Plus Graphics 1536 MB , Sequoia 15.2
Try this. Next time it won't eject, use CMD-Tab to see what apps are running. Quit them all (but Finder, that one won't quit and will immediately restart). Then see if you can unmount the drive.
It also might be Spotlight indexing the drive that has it open.
As for the fingers-crossed situation, I would suggest that if these images are important to you (I know they are) I would have a duplicate of the library on a different drive and use something like Carbon Copy Cloner or ChronoSync to keep them in sync. I lost several thousand images when my hard drive died AND my backup drive died the same day, so now I have 4 copies, all on different drives (one is a RAID array) connected different ways (USB, Network, Internal) because I'm paranoid about it.
For once I'm ahead of you Jake

From the Apple Support Community:
The system Photos Library is always in use as long as you are signed into your user account. The background processes started by Photos are always expecting the system photos library to be available.
In addition, they are suggesting leaving it plugged in all the time. WHAT?
If possible, keep the volume connected cited at all times (this is highly inconvenient when using a MacBook Air and not a Desktop computer.
I guess that leaves Spotlight as the culprit? Can Spotlight be turned off to prove theory?