Welcome to the forum cornishpete .....
Mate my advice would be, considering its already been set up before is to put in the DVD and reboot while holding down *c* ..... the press english ... Then follow on to erase the HD via Disk Utility. Then when that closes it will bring you to the installer window. Do what you need to do to start installing the OS ... When its all done 40 mins or so its all yours. Start up and go through the Mac setup and registering it ....
Once your up and going here is a few things to look at that i posted for a new Mac user not too long ago... If need any more answers be sure to pop in ....
Mac Switching 101
Mac 101
MacTricksAndTips ~ 100 Essential Mac Apps
Mac OS Keyboard Shortcuts
Mac OS Menu Bar Items
Mac downloads ~ Apple
So there is a bit of reading there. As i goes for Apps we dont know what you are into, but ill list a few that most people have and you can look them up in the 100 Essential Apps URL i gave ...
Adium ~ Chat Client
Growl Notifications
SuperDuper or CarbonCopyCloner ~ Both make bootable copies of your HD
HandBrake ~ Video Converting
Burn ~ As it says A Burning App
Transmission ~ p2p client
Skitch ~ Screen capture and more
VLC ~ Video player that plays most codecs and does a lot more
Perian and Flip4Mac Makes watching certain codecs easier ... This is Essential IMHO
Audacity ~ Play with Music App
CandyBar ~ Mods all your icons, and dock
MainMenu or Oynx ~ Does the same as Disk utility only more thorough
Quicksilver ~ Works like Spotlight but way way better and does so much more
StuffitExpander ~ Opens Zip and rar files and more
Lil Snitch ~ Firewall type App that looks at your incoming and outgoing traffic
and last but certainly not least .....
AppTrap ~ Once installed it sits in System Preferences and deletes all associated files of anything that you put in the trash ...
Enough to get ya started
Cheers