Sorry for the taciturnity, but I'm not seeing a pattern. My default email is Gmail and I'm using OS 10.6.8. I just tried clicking a bunch of links in the Chrome browser history, plus several "contact us" links in public and private sector websites (which open Gmail as I'd expect), but was unable to replicate the unexpected opening of Mail. The problem has been going on for a few weeks, but I've not seen it today, so maybe there was a self-healing with the last restart of the computer. Thanks for your patience.