Print options come from the driver not Word, however, you may be missing them as they are in a different location that you are used to in Windows.
After selecting File > Print, click on the small box with an arrow in it to the right of the "Printer:" selection box. When the arrow is pointing up, your options will be maximized.
Click on "Copies and Pages". A drop down box will open. Select "Paper Type/Quality". This contains the options you are looking for.
If you do not have the above on your Mac, then you need to find a different printer driver, which can be a frustrating activity.