Welcome to the Adobe users family

I love their stuff!
I've been working with DW for a long time now. CS2, CS3 and now CS4. I don't use any of the other software, but honestly wish I knew how to work with them and design flash, etc.
Anyway...My favorite resource when I was just learning dreamweaver and one that I still use today to check back for things is
Lynda.com (dont worry not an affiliate link or anything).
It is something like $29 a month or some where along those lines, but with step by step video instruction I think it's very much worth it. I know that you can also find some pretty good step by step videos online some place for free as well I just prefer lynda.
Good luck and show us your work sometime!