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I own iphoto 08 and I know its not possible with that version.
If you really wanted to you could download GIMP. Its a free application that will allow you to crop your brother and save him separately.
Then in iphoto just changed the whole picture to black and white.
Then reload the picture now black and white with GIMP and add your coloured version of your brother.
Hope that helps if you have any questions just ask.
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FOR THE HORDE!!!
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